File:External-stimulation-controllable-heat-storage-ceramics-ncomms8037-s7.ogv
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[edit]DescriptionExternal-stimulation-controllable-heat-storage-ceramics-ncomms8037-s7.ogv |
English: Supplementary Movie 6 Mechanism of pressure-induced phase transition from stripe-type-λ-Ti3O5 to β-Ti3O5. This movie shows the mechanism of pressure-induced phase transition using the thermodynamic model proposed by Slichter and Drickamer. Gibbs free energy (G) versus λ-Ti3O5 fraction (x) curves show that λ-Ti3O5 phase (blue) is maintained at all temperatures due to the energy barrier originated from cooperative interaction between the two phases. Then, the 300 K curve is focused, showing its pressure dependence. At 60 MPa, the energy barrier disappears, and λ-Ti3O5 phase converts into β-Ti3O5 phase (red). Finally, heat storage process from β-Ti3O5 to λ-Ti3O5 is shown with G versus x and x versus temperature curves. Such a metal oxide is the first example. |
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Source | Video file from Tokoro H, Yoshikiyo M, Imoto K, Namai A, Nasu T, Nakagawa K, Ozaki N, Hakoe F, Tanaka K, Chiba K, Makiura R, Prassides K, Ohkoshi S (2015). "External stimulation-controllable heat-storage ceramics". Nature Communications. DOI:10.1038/ncomms8037. PMID 25962982. PMC: 4432584. | ||
Author | Tokoro H, Yoshikiyo M, Imoto K, Namai A, Nasu T, Nakagawa K, Ozaki N, Hakoe F, Tanaka K, Chiba K, Makiura R, Prassides K, Ohkoshi S | ||
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![]() ![]() This file is licensed under the Creative Commons Attribution 4.0 International license.
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current | 07:47, 1 November 2016 | 1 min 41 s, 1,024 × 768 (8.87 MB) | Open Access Media Importer Bot (talk | contribs) | Automatically uploaded media file from Open Access source. Please report problems or suggestions here. |
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Author | Tokoro H, Yoshikiyo M, Imoto K, Namai A, Nasu T, Nakagawa K, Ozaki N, Hakoe F, Tanaka K, Chiba K, Makiura R, Prassides K, Ohkoshi S |
Usage terms | http://creativecommons.org/licenses/by/4.0/ |
Image title | Mechanism of pressure-induced phase transition from stripe-type-λ-Ti3O5 to β-Ti3O5. This movie shows the mechanism of pressure-induced phase transition using the thermodynamic model proposed by Slichter and Drickamer. Gibbs free energy (G) versus λ-Ti3O5 fraction (x) curves show that λ-Ti3O5 phase (blue) is maintained at all temperatures due to the energy barrier originated from cooperative interaction between the two phases. Then, the 300 K curve is focused, showing its pressure dependence. At 60 MPa, the energy barrier disappears, and λ-Ti3O5 phase converts into β-Ti3O5 phase (red). Finally, heat storage process from β-Ti3O5 to λ-Ti3O5 is shown with G versus x and x versus temperature curves. Such a metal oxide is the first example. |
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Language | English |