File:Titanium(IV)-fluoride-from-xtal-unit-cell-b-3D-bs-17.png

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Ball-and-stick model of the unit cell as part of the crystal structure of titanium tetrafluoride, TiF4.

The crystal structure consists of three, crystallographically different Ti4+ cations which are surrounded octahedrally by six F– ions each. Each TiF6 octahedron is connected to two other TiF6 octahedra equatorially, creating a ring with the composition Ti3F15. By connecting these rings axially with other rings, isolated columns are formed.

Structure determined by single-crystal X-ray diffraction reported in Z. Anorg. Allg. Chem. 1995, 621, 1227–1231 and is available as CSD entry 1639008 and ICSD entry 78737.

CAS® Registry Number: 7783-63-3

Colour code:

  Titanium, Ti: light grey
  Fluorine, F: light green
Model manipulated and image generated in CCDC Mercury 2022.3.0.
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Author Simon Weber
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Public domain This work has been released into the public domain by its author, Chem Sim 2001. This applies worldwide.

In some countries this may not be legally possible; if so:
Chem Sim 2001 grants anyone the right to use this work for any purpose, without any conditions, unless such conditions are required by law.

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current19:06, 21 April 2023Thumbnail for version as of 19:06, 21 April 20231,136 × 1,818 (95 KB)Chem Sim 2001 (talk | contribs)== {{int:filedesc}} == {{Information | Description = Ball-and-stick model of the unit cell as part of the crystal structure of titanium tetrafluoride, TiF<sub>4</sub>. Structure determined by single-crystal X-ray diffraction reported in [https://doi.org/10.1002/zaac.19956210720 ''Z. Anorg. Allg. Chem.'' '''1995''', ''621'', 1227–1231] and is available as [[...

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