File:Schultze-Tiemann method for the determination of nitric nitrogen in drinking water (Alessandri 1895.33).png

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Schultze-Tiemann method for the determination of nitric nitrogen in drinking water

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Italiano: Due litri di acqua da analizzare sono ridotti a 50 mL, ed inseriti in un pallone da 150 mL. Per raffreddamento della soluzione posta ad ebollizione si crea un debole vuoto nel sistema, ed aprendo B si inseriscono tramite A 20 mL di cloruro ferroso saturo e poi altrettanti di acido cloridrico HCl. Per ulteriore riscaldamento a sistema chiuso si sviluppano vapori di HCl e ossido nitrico NO, che vengono raccolti in una campana graduata invertita riempita di NaOH al 10%. Per misurazione del volume di NO raccolto è possibile ricavare la quantità di azoto nitrico nell'acqua di partenza.
English: Two liters of drinking water are boiled down to 50 mL, and inserted into a 150 mL round-bottom flask. The system is boiled down to a few mL and the clips closed, so that by cooling there is a mild vacuum inside. The clip B is opened, and tube A immersed in a beaker with 20 mL of saturated ferrous chloride, which is aspirated inside, followed by HCl. The clips are closed and by further heating, a pressure of NO gas and HCl vapours are released and collected into a graduated inverted tube in 10% NaOH. By measurement of the volume of NO it is possible to determine the original amount of nitrates in the sample.
Date
Source Alessandri, P. E. Analisi Volumetrica Applicata Ai Prodotti Commerciali e Industriali; Ulrico Hoepli: Milano, 1895.
Author valeg96

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This work is in the public domain in its country of origin and other countries and areas where the copyright term is the author's life plus 70 years or fewer.


This work is in the public domain in the United States because it was published (or registered with the U.S. Copyright Office) before January 1, 1929.

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