File:ActivityCoefficientAnimation.gif
Original file (960 × 576 pixels, file size: 43 KB, MIME type: image/gif, looped, 5 frames, 6.0 s)
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DescriptionActivityCoefficientAnimation.gif |
English: Animation showing how adding NaCl to a solution can change the enthalpy of a reaction seemingly unrelated to the Na+ or Cl- ions. This is one of many phenomena that can be quantified using the idea of "activity coefficients". (The NaCl changes the "ionic strength" of the solution, which alters the activity coefficients of every ion in the solution, see "Debye–Hückel equation".)
The animation shows a hypothetical reaction A- + A- --> A22-, in pure water (left) and salt-water (right). As the two A- anions approach each other, they experience a stronger and stronger repulsive electric force (orange arrows). However, the repulsion is always much weaker in saltwater than in pure water, because each A- anion can attract a cloud of Na+ cations to screen its charge. Therefore, adding NaCl changes the enthalpy of reaction. |
Date | |
Source | Own work |
Author | Sbyrnes321 |
Images made and exported to gif with MS Powerpoint, animated with Photobie.
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Public domainPublic domainfalsefalse |
I, the copyright holder of this work, release this work into the public domain. This applies worldwide. In some countries this may not be legally possible; if so: I grant anyone the right to use this work for any purpose, without any conditions, unless such conditions are required by law. |
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current | 07:41, 12 July 2010 | 960 × 576 (43 KB) | Sbyrnes321 (talk | contribs) | {{Information |Description={{en|1=Animation showing how adding NaCl to a solution can change the enthalpy of a reaction seemingly unrelated to the Na+ or Cl- ions. This is one of many phenomena that can be quantified using the idea of "activity coefficien |
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