File:Tryptophan-Stoffwechsel.svg
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[edit]DescriptionTryptophan-Stoffwechsel.svg |
Deutsch: Stoffwechsel von L-Tryptophan in Melatonin (über Serotonin) sowie Niacin Siehe auch Tryptophan-Stoffwechsel bei Wikibooks |
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Date | |||||
Source | Own work | ||||
Author | Krishnavedala | ||||
Permission (Reusing this file) |
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\documentclass[12pt,border=1pt,tikz,class=scrartcl,multi=false]{standalone}
\usepackage{times}
\usepackage[T1]{fontenc}
\usepackage[latin1]{inputenc}
\usepackage{mathtools,amssymb}
\usepackage{pgfplots}
\pgfplotsset{compat=1.12}
\usetikzlibrary{positioning,calc,arrows,fit,backgrounds,decorations.text,shapes}
\usepackage{chemfig,chemmacros}
\renewcommand*{\familydefault}{\sfdefault}
\renewcommand*\printatom[1]{\ensuremath{\mathsf{#1}}}
\setatomsep{1.7em}
\setdoublesep{.6ex}
\setarrowdefault{,1,ultra thick}
\setbondstyle{very thick,cap=but}
\definesubmol\nobond{-[,0.2,,,draw=none]}
\pagestyle{empty}
\thispagestyle{empty}
\begin{document}
\renewcommand{\baselinestretch}{.5}
\begin{tikzpicture} [>=latex,inner sep=2pt]
\node (l1) {\chemfig{
O=[::30](-[::-60]OH)-[::60](-[::-60]NH_2)
<:[::60]-[::60]
*5(-*6(-=-=-=)--[,,,2]HN-=)
}};
\node at ($(l1)+(8.5,0)$) (r1) {\chemfig{
O=[::30](-[::-60]OH)-[::60](-[::-60]NH_2)
<:[::60]-[::60](=[::60,,,,red]\color{red}{O})
-[::-60]*6(=-=-=(-NH-[::-60](-[::-60,,,,red]\color{red}{H})=[::60,,,,red]\color{red}{O})-)
}};
\node at ($(l1)-(0,5)$) (l2) {\chemfig{
O=[::30](-[::-60]OH)-[::60](-[::-60]NH_2)
<:[::60]-[::60]
*5(-*6(-=(-[,,,,red]\color{red}{H}|\color{red}{O})-=-=)--[,,,2]HN-=)
}};
\node at ($(l2)-(0,5)$) (l3) {\chemfig{
NH_2-[:-150,,,,red]-[::-60,,,,red]-[::60]
*5(-*6(-=(-HO)-=-=)--[,,,2]HN-=)
}};
\node at ($(l3)-(0,5)$) (l4) {\chemfig{
\color{red}{CH_3}-[:-150,,,,red](=[::60,,,,red]\color{red}{O})-[::-60,,,,red]\chemabove{N}{H}
-[::60]-[::-60]-[::60]
*5(-*6(-=(-HO)-=-=)--[,,,2]HN-=)
}};
\node at ($(l4)-(0,5)$) (l5) {\chemfig{
CH_3-[:-150](=[::60]O)-[::-60]\chemabove{N}{H}
-[::60]-[::-60]-[::60]
*5(-*6(-=(-O-[::60,1.5,,,red]\color{red}{H_3C})-=-=)--[,,,2]HN-=)
}};
\node at ($(l2)+(8.5,0)$) (r2) {\chemfig{
O=[::30](-[::-60]OH)-[::60](-[::-60]NH_2)
<:[::60]-[::60](=[::60]O)
-[::-60]*6(=-=-=(-\color{red}{N}|\color{red}{H_2})-)
}};
\node at ($(l3)+(8.5,0)$) (r3) {\chemfig{
O=[2](-[::-60]OH)-[::60]
*6(-=-\color{red}{C}(-[4,.6,,,draw=none]\color{red}{HO})
-[,,,,draw=none]\color{red}{C}(-[4,.8,,,draw=none]\color{red}{HOO})-(-NH_2)=)
}};
\node at ($(l4)+(8.5,0)$) (r4) {\chemfig{
*6(-[,,,,red]\color{red}{N}
=(-(-[::60]OH)=[::-60]O)
-(-(-[::-60]OH)=[::60]O)
=-=)
}};
\node at ($(l5)+(8.5,0)$) (r5) {\chemfig{
*6(-N
=[,,,,red]-[,,,,red](-(-[::-60]OH)=[::60]O)
=-=)
}};
\node [below=.1em of l5] {\textbf{Melatonin}};
\node [below=.1em of r5] {\textbf{Niacin}};
\draw [->,very thick] (l1.east) -- (r1.west)
node [pos=.5,above] {\footnotesize Indolamin--}
node [pos=.5,below] {\footnotesize 2,3--Dioxygenase};
\draw [->,very thick] ($(l1.south)-(0,.2)$) node [left] {\textbf{L-Tryptophan}} -- ($(l2.north)-(0,.5)$)
node [pos=.5,right,text width=5em,text centered] {\footnotesize Tryptophan--Hydroxylase};
\draw [->,very thick] ($(l2.south)-(0,.2)$) -- ($(l3.north)-(0,.7)$)
node [pos=0,left,text width=5em] {\footnotesize5--Hydroxy--tryptophan}
node [pos=.5,right,text centered,text width=6em] {\footnotesize Aromatische--L--Aminos\"aure-Decarboxylase};
\draw [->,very thick] ($(l3.south)-(0,.2)$) -- ($(l4.north)-(0,.7)$)
node [pos=0.1,left=1,text width=5em] {\footnotesize5--Hydroxy--tryptamin\\(5-HT)}
node [pos=0,above right=1,text width=5em] {\textbf{Serotonin}}
node [pos=.5,right,text centered,text width=6em] {\footnotesize N--Acetyltransferase};
\draw [->,very thick] ($(l4.south)-(0,.2)$) -- ($(l5.north)-(0,.7)$)
node [pos=0.1,left=1,text width=4em] {\footnotesize N--Acetyl 5--HT}
node [pos=.5,right,text centered,text width=8em] {\footnotesize5--Hydroxyindol--\\O--Methyl--Transferase};
\draw [->,very thick] ($(r1.south)-(0,.2)$) -- ($(r2.north)-(0,.5)$)
node [pos=.5,right,text centered,text width=6em] {\footnotesize Formamidase};
\node [right=0pt of r1,text width=5em] {\footnotesize N'--Formyl--\\kynurenin};
\draw [->,ultra thick] ($(r2.south)-(0,.2)$) -- (r3.north);
\node [right=0pt of r2,text width=5em] {\footnotesize Kynurenin};
\draw [->,very thick] ($(r3.south)-(0,.2)$) -- ($(r4.north)-(0,.5)$)
node [pos=.5,right,text centered,text width=6em] {\footnotesize nicht-enzymatische\\Cyclisierung};
\node [right=0pt of r3,text width=6em] {\footnotesize 2--Amino--3--carboxy--mucons\"aure--semialdehyd};
\draw [->,ultra thick] ($(r4.south)-(0,.2)$) -- (r5.north);
\node [right=0pt of r4,text width=5em] {\footnotesize Chinolins\"aure};
\end{tikzpicture}
\end{document}
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Date/Time | Thumbnail | Dimensions | User | Comment | |
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current | 19:21, 3 March 2016 | 595 × 851 (291 KB) | Kopiersperre (talk | contribs) | =={{int:filedesc}}== {{Information |Description ={{de|1=Stoffwechsel von L-Tryptophan in Melatonin (über Serotonin) sowie Niacin<br /> Siehe auch [[b:de:Biochemie und Pathobioche... |
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Width | 595.01373 |
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Height | 851.27753 |