File:Chlorine dioxide-electrons and angle.svg
Original file (SVG file, nominally 525 × 296 pixels, file size: 13 KB)
Captions
Summary
[edit]DescriptionChlorine dioxide-electrons and angle.svg |
English: Chlorine_dioxide.png new as SVG and with angle/bondlength. Note: This is more or less the structure given by Pauling on page 264 of his General Chemisty, although he puts three dots between the left-hand oxygen and the chlorine, as well as a line segment, instead of two line segments and a dot on the chlorine as we have here. But the 1933 paper by Brockway differs from this in having a single bond going to the other oxygen, and three lone pairs on that oxygen. That makes more sense, as it puts only nine electrons around the chlorine, rather than eleven in Pauling's diagram or in this diagram. Actually, Brocksay (who collaborated with Pauling) means his diagram to represent a mixture of a Lewis electronic structure with one lone pair and a lone electron on the chlorine, and three lone pairs on the left-hand oxygen, and a structure with two lone pairs on the chlorine and two lone pairs and a lone electron on that oxygen. Each of these two structures also has a single bond going to each oxygen. In these structures, each atom is surrounded by seven or eight electrons. Brockway says that the three-electron bond is equivalent to half a single bond. This gives a total of two and a half single bonds in the molecule, not two double bonds or a double bond plus one and a half single bonds as in this diagram. Of course, Brockway mentions that in reality we have a resonance between the structure with the three-electron bond going to one oxygen and the structure with it going to the other oxygen.
Deutsch: Chlorine_dioxide.png neu und mit Elektronenpaaren zusaetzlich zu Winkel/Bindungslaenge |
Date | |
Source | Own work |
Author | Iridos / FK1954 |
Licensing
[edit]Public domainPublic domainfalsefalse |
I, the copyright holder of this work, release this work into the public domain. This applies worldwide. In some countries this may not be legally possible; if so: I grant anyone the right to use this work for any purpose, without any conditions, unless such conditions are required by law. |
The copyright holder of this work allows anyone to use it for any purpose including unrestricted redistribution, commercial use, and modification.
Please check the source to verify that this is correct. In particular, note that publication on the Internet, like publication by any other means, does not in itself imply permission to redistribute. Files without valid permission should be tagged with {{subst:npd}}. Usage notes:
|
File history
Click on a date/time to view the file as it appeared at that time.
Date/Time | Thumbnail | Dimensions | User | Comment | |
---|---|---|---|---|---|
current | 23:08, 28 September 2016 | 525 × 296 (13 KB) | FK1954 (talk | contribs) | Degree symbol removed | |
23:18, 22 January 2010 | 420 × 236 (16 KB) | Iridos (talk | contribs) | {{Information |Description={{en|1=Chlorine_dioxide.png new as SVG and with angle/bondlength}} {{de|1=Chlorine_dioxide.png neu und mit Elektronenpaaren zusaetzlich zu Winkel/Bindungslaenge}} |Source={{own}} |Author=Iridos |Date= |Permission |
You cannot overwrite this file.
File usage on Commons
The following 2 pages use this file:
File usage on other wikis
The following other wikis use this file:
- Usage on ca.wikipedia.org
- Usage on de.wikipedia.org
- Usage on fi.wikipedia.org
- Usage on ja.wikipedia.org
- Usage on pl.wikipedia.org
Metadata
This file contains additional information such as Exif metadata which may have been added by the digital camera, scanner, or software program used to create or digitize it. If the file has been modified from its original state, some details such as the timestamp may not fully reflect those of the original file. The timestamp is only as accurate as the clock in the camera, and it may be completely wrong.
Width | 148.17mm |
---|---|
Height | 83.41mm |